Perylenediimide promoted charge transfer in tetracyano butadiene–triphenylamine (TCBD–TPA) and expanded-tetracyano butadiene–triphenylamine (DCNQ–TPA) push–pull conjugates
The significance of perylenediimide (PDI) in promoting excited charge transfer in push-pull systems carrying TCBD-TPA and DCNQ-TPA, synthesised <i>via</i> Pd(II)-catalysed Sonogashira cross-coupling reaction followed by [2+2] cycloaddition retroelectrocyclization (CA-RE) reaction, is demonstrated using femtosecond transient absorption and other pertinent methods.
Authors
- Ajyal Z. Alsaleh (ORCID: https://orcid.org/0000-0002-2361-8888)
- Yogajivan Rout
- Francis Wallace D'Souza (ORCID: https://orcid.org/0000-0003-3815-8949)
- Rajneesh Misra (ORCID: https://orcid.org/0000-0003-3225-2125)
- Ram R. Kaswan
- Mohd Wazid
Institutions
- University of North Texas (US)
- Indian Institute of Technology Indore (IN)
- Imam Abdulrahman Bin Faisal University (SA)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00578g
- Citations
- 10
- Primary Topic
- Photochemistry and Electron Transfer Studies
- Type
- article
- Field-Weighted Citation Impact
- 17.53