<i>In situ</i> synthesis of a Bi<sub>2</sub>O<sub>3</sub>/Bi<sub>2</sub>S<sub>3</sub> composite heterojunction for the electrochemical characterization of supercapacitors

This study employs a two-step hydrothermal method to <i>in situ</i> introduce sulfur into a Bi<sub>2</sub>O<sub>3</sub> matrix. The synthesized material displays a specific capacitance of 305.57 F g<sup>-1</sup> (2 A g<sup>-1</sup>) and achieves a cycling stability of 94.12% (10 A g<sup>-1</sup>), evidencing the enhancement of both capacitance and cycling stability attributed to the heterojunction. The existence of a built-in electric field was confirmed <i>via</i> theoretical calculations, highlighting the interactions between the electrode materials and ions. In addition, devices were constructed to demonstrate the practicality in real-world applications. This study proposes an effective methodology for the <i>in situ</i> synthesis of heterojunctions, offering fresh perspectives on the development of electrode materials for supercapacitors.

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Publication Details

Journal
Dalton Transactions
Published
2025-01-01
DOI
https://doi.org/10.1039/d5dt00026b
Citations
2
Primary Topic
Supercapacitor Materials and Fabrication
Type
article
Field-Weighted Citation Impact
0.85

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article

In situ synthesis of a Bi2O3/Bi2S3 composite heterojunction for the electrochemical characterization of supercapacitors

Yulong Deng, Jinming Cai, Chunming Deng, Xiaoming Cai et al.
2 citations
Dalton Transactions
Supercapacitor Materials and Fabrication
0.85
article

In situ synthesis of a Bi2O3/Bi2S3 composite heterojunction for the electrochemical characterization of supercapacitors

Yulong Deng, Jinming Cai, Chunming Deng, Xiaoming Cai, Jinhua Zheng, Honglin Tan, Wenting Chen
article en
2 citations

Abstract

This study employs a two-step hydrothermal method to <i>in situ</i> introduce sulfur into a Bi<sub>2</sub>O<sub>3</sub> matrix. The synthesized material displays a specific capacitance of 305.57 F g<sup>-1</sup> (2 A g<sup>-1</sup>) and achieves a cycling stability of 94.12% (10 A g<sup>-1</sup>), evidencing the enhancement of both capacitance and cycling stability attributed to the heterojunction. The existence of a built-in electric field was confirmed <i>via</i> theoretical calculations, highlighting the interactions between the electrode materials and ions. In addition, devices were constructed to demonstrate the practicality in real-world applications. This study proposes an effective methodology for the <i>in situ</i> synthesis of heterojunctions, offering fresh perspectives on the development of electrode materials for supercapacitors.

Dalton TransactionsVol. 54(17)
Kunming University of Science and Technology (CN)
National Natural Science Foundation of China, Yunnan Provincial Department of Education
Openalex Percentile: Top 29%
Supercapacitor Materials and Fabrication
0.85
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