Characterization of CYA:RE3+ powder and security ink for luminescent tagging of documents

The luminescent ceramic powders CaYAl<sub>3</sub>O<sup>7</sup> (CYA) with various doping concentration of Eu<sup>3+</sup> ions (0.5 – 40 at.%) were synthesized by solid state method. The phase purity, morphology as well as photoluminescence properties of the CaYAl<sub>3</sub>O<sub>7</sub>:Eu<sup>3+</sup> were investigated as a function of active ions doping. The concentration quenching effect was observed for powders doped above 30 at.% of Eu<sup>3+</sup> ions. The XRD analysis confirmed dominant content of the tetragonal CYA phase and high purity of the samples. The PLE spectra were measured in UV-VIS region and the high intense PL spectra consist of three bands with maximum peak at 702.4 nm due to <sup>7</sup>F<sub>0</sub> → <sup>5</sup>D<sub>4</sub> transition were observed. The obtained CYA:Eu<sup>3+</sup> powder was investigated for luminescent tagging application. The material was successfully incorporated into ink base and printed on security paper using screen-printing method.

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Published
2025-04-04
DOI
https://doi.org/10.1117/12.3056457
Primary Topic
Handwritten Text Recognition Techniques
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article
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article

Characterization of CYA:RE3+ powder and security ink for luminescent tagging of documents

Kamila Leśniewska‐Matys, Krzysztof Skupień, J. Zawistowska, Meldra Ķemere et al.
Handwritten Text Recognition Techniques
article

Characterization of CYA:RE3+ powder and security ink for luminescent tagging of documents

Kamila Leśniewska‐Matys, Krzysztof Skupień, J. Zawistowska, Meldra Ķemere, Anna Stępień, Oskar Bogucki, Anatolijs Šarakovskis, Agnieszka B. Malinowska, M. Romaniec, Anna Kozłowska, Monika Binkowska, Michał Kukielski, Aleksandra Pantoł-Boczoń
article en

Abstract

The luminescent ceramic powders CaYAl<sub>3</sub>O<sup>7</sup> (CYA) with various doping concentration of Eu<sup>3+</sup> ions (0.5 – 40 at.%) were synthesized by solid state method. The phase purity, morphology as well as photoluminescence properties of the CaYAl<sub>3</sub>O<sub>7</sub>:Eu<sup>3+</sup> were investigated as a function of active ions doping. The concentration quenching effect was observed for powders doped above 30 at.% of Eu<sup>3+</sup> ions. The XRD analysis confirmed dominant content of the tetragonal CYA phase and high purity of the samples. The PLE spectra were measured in UV-VIS region and the high intense PL spectra consist of three bands with maximum peak at 702.4 nm due to <sup>7</sup>F<sub>0</sub> → <sup>5</sup>D<sub>4</sub> transition were observed. The obtained CYA:Eu<sup>3+</sup> powder was investigated for luminescent tagging application. The material was successfully incorporated into ink base and printed on security paper using screen-printing method.

Łukasiewicz Research Network (PL), Nano Hydrophobics (United States) (US), University of Latvia (LV)
Openalex Percentile: Top 95%
Handwritten Text Recognition Techniques
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