Flexible porous organic polymers with 1,2-diol subunits favoring the high loading of Pd nanoparticles
In recent years, the flexibility of porous organic polymers has demonstrated very unique properties during their applications. This paper reports a novel soluble porous polymer (named BIT-POP-75 and BIT-POP-75-OH) with 1,2-diketone and 1,2-diol subunits in the flexible polymer chain using contorted subunits. The solubility of the porous polymer and the flexible chelating 1,2-diol moiety facilitates the high loading and uniform dispersion of Pd nanoparticles to give the catalyst Pd@BIT-POP-75-OH, which shows high efficiency (<i>k</i><sub>app</sub> = 0.965 min<sup>-1</sup>) for the catalytic reduction of 4-nitrophenol with good recyclability (10 cycles).
Authors
- Hanyuan Chen (ORCID: https://orcid.org/0000-0001-6448-1163)
- Jin‐Xiu Zhou
- Mu‐Hua Huang (ORCID: https://orcid.org/0000-0002-3563-7381)
- Z. Wang (ORCID: https://orcid.org/0000-0002-2720-7103)
- Nicolas Bogliotti (ORCID: https://orcid.org/0000-0002-6076-2125)
- Yan Liu (ORCID: https://orcid.org/0000-0002-7560-519X)
- Ran Guo (ORCID: https://orcid.org/0000-0003-1451-3467)
- Boya Kuang
Institutions
- Beijing Institute of Technology (CN)
- Centre National de la Recherche Scientifique (FR)
- Université Paris-Saclay (FR)
- Laboratoire de Photophysique et Photochimie Supramoléculaires et Macromoléculaires (FR)
Publication Details
- Journal
- Nanoscale
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nr00049a
- Primary Topic
- Nanomaterials for catalytic reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Natural Science Foundation of China
- Beijing Municipal Natural Science Foundation