Variational Approach to Entangled Non-Hermitian Open Systems

The pseudomode model effectively captures the nonperturbative dynamics of open quantum systems with significantly reduced degrees of freedom. However, it is limited by the exponential growth of the Hilbert space dimension. To overcome the computational challenges, we propose a novel method that combines the multiple Davydov Ansatz with the Choi-Jamiolkowski isomorphism. Within this framework, the Lindblad equation is transformed into the non-Hermitian Schrödinger equation in a double Hilbert space, with its dynamics determined using the time-dependent variational principle. Three cases are calculated to demonstrate the effectiveness of the proposed method. We first discuss how the Davydov Ansatz works for the model with a single pseudomode. Extending the method to multiple pseudomodes, we show that the Ansatz effectively circumvents the exponential growth of the Hilbert space. Additionally, the method is also capable of addressing potential intersections that emerge in multibath scenarios. This approach offers potential applicability to various types of pseudomode models and other dissipative systems, providing a promising tool for the studies of open quantum dynamics.

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Publication Details

Journal
Journal of Chemical Theory and Computation
Published
2025-04-04
DOI
https://doi.org/10.1021/acs.jctc.5c00018
Citations
2
Primary Topic
Quantum chaos and dynamical systems
Type
article
Field-Weighted Citation Impact
2.65
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article

Variational Approach to Entangled Non-Hermitian Open Systems

Jiarui Zeng, Yang Zhao, Wen-Qiang Xie
2 citations
Journal of Chemical Theory and Computation
Quantum chaos and dynamical systems
2.65
article

Variational Approach to Entangled Non-Hermitian Open Systems

Jiarui Zeng, Yang Zhao, Wen-Qiang Xie
article en
2 citations

Abstract

The pseudomode model effectively captures the nonperturbative dynamics of open quantum systems with significantly reduced degrees of freedom. However, it is limited by the exponential growth of the Hilbert space dimension. To overcome the computational challenges, we propose a novel method that combines the multiple Davydov Ansatz with the Choi-Jamiolkowski isomorphism. Within this framework, the Lindblad equation is transformed into the non-Hermitian Schrödinger equation in a double Hilbert space, with its dynamics determined using the time-dependent variational principle. Three cases are calculated to demonstrate the effectiveness of the proposed method. We first discuss how the Davydov Ansatz works for the model with a single pseudomode. Extending the method to multiple pseudomodes, we show that the Ansatz effectively circumvents the exponential growth of the Hilbert space. Additionally, the method is also capable of addressing potential intersections that emerge in multibath scenarios. This approach offers potential applicability to various types of pseudomode models and other dissipative systems, providing a promising tool for the studies of open quantum dynamics.

Journal of Chemical Theory and ComputationVol. 21(8)
Nanyang Technological University (SG), Hainan University (CN)
Openalex Percentile: Top 11%
Quantum chaos and dynamical systems
2.65
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Variational Approach to Entangled Non-Hermitian Open Systems — Jiarui Zeng, Yang Zhao, et al. · Journal of Chemical Theory and Computation (2025) | TGRS Research Map | TGRS