Na<sub>2</sub>PbB<sub>6</sub>O<sub>10</sub>SO<sub>4</sub> and Ca<sub>2.58</sub>Pb<sub>0.42</sub>B<sub>6</sub>O<sub>11</sub>SO<sub>4</sub>: first borate–sulfates featuring 3D porous borate anionic frameworks
Two new borate–sulfates form unique three-dimensional (3D) porous frameworks with embedded [SO 4 ] units. The transition from structure I to II is driven by differences in cationic radii, leading to distinct 3D porous borate anionic frameworks.
Authors
- Shaohuan Liu
- Xueling Hou (ORCID: https://orcid.org/0000-0003-3682-7387)
- Fangfang Zhang (ORCID: https://orcid.org/0000-0002-9628-1817)
- Zi‐Jian Li (ORCID: https://orcid.org/0000-0002-3887-0234)
- H. Pei
Institutions
- Shihezi University (CN)
- Xinjiang Production and Construction Corps (CN)
- Xinjiang Technical Institute of Physics & Chemistry (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00394f
- Primary Topic
- Crystal Structures and Properties
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Chinese Academy of Sciences