Synergism between cyclopentadienyl and amidinate ligands affording anionic scandium terminal imido complexes
The combination of Cp* and amidinate ligands leads to the formation of the first anionic rare-earth( iii ) terminal imido complexes, which show unique reactivity towards phenylsilane, isonitrile, and W(CO) 6 .
Authors
- Tianyu Li (ORCID: https://orcid.org/0000-0002-6389-9282)
- Wen‐Xiong Zhang (ORCID: https://orcid.org/0000-0003-0744-2832)
- Junnian Wei (ORCID: https://orcid.org/0000-0001-9733-803X)
- Miaomiao Zhu (ORCID: https://orcid.org/0000-0001-7306-0336)
- Dajiang Huang (ORCID: https://orcid.org/0009-0009-3479-050X)
Institutions
- Peking University (CN)
- Beijing National Laboratory for Molecular Sciences (CN)
- State Key Laboratory of Rare Earth Materials Chemistry and Application
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00390c
- Citations
- 3
- Primary Topic
- Organometallic Complex Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 2.81