Subduction and melting of biogenic and ferromanganese sediments as evidenced by sub-Moho granitoids

Mantle-hosted granitoids (MHG) from the supra-subduction Samail ophiolite in Oman and the United Arab Emirates exhibit diverse compositions, highlighting variations in petrogenesis and source contributions. Previous isotopic data indicate these MHG originated through the interaction of sediment-derived with basaltic melts from an underthrust oceanic plate within the mantle wedge. The sedimentary contribution was attributed to the partial melting of pelitic to siliceous (bio-siliceous) material atop the subducted plate based on elevated zircon δ 18 O values (∼14–28 ‰). To further evaluate this hypothesis on Samail MHG petrogenesis and source contribution, we present new and compiled radiogenic (Sr-Nd-Hf-Pb) and stable (O-Li-H) isotopes, along with zircon trace element analyses. The variable Sr and Pb isotopic signature support a mixed origin involving altered mafic and sedimentary sources in the formation of the MHG. Negative whole-rock εNd, coupled with elevated δ 7 Li in muscovite suggest the involvement of sedimentary sources and particularly those resembling deep-sea ferromanganese-rich sediments. We propose a new model identifying ferromanganese sediments as a potential source given their widespread distribution across the ocean floor, broad range of δ 18 O (up to 29.5 ‰), slightly positive Hf values, seawater-like δ 7 Li signatures (median of ∼27 ‰), and zircon trace element compositions lacking a signature of monazite co-precipitation, which match the signatures required for the genesis of the Samail MHG. Preservation of oceanic lithosphere in the geological record is limited, and MHG in ophiolites are uncommon. Therefore, the Samail MHG are key examples of crustal materials transported to the mantle, with implications for mantle heterogeneity and arc mantle redox budget. • Isotopes of Samail mantle-hosted granitoids reflect sediment-basalt interaction • Isotopes and trace elements suggest Fe-Mn sediments as a source for mantle-hosted granitoids. • These granitoids serve as key examples of crustal materials recycled into the mantle.

Authors

Institutions

Publication Details

Journal
Chemical Geology
Published
2025-04-04
DOI
https://doi.org/10.1016/j.chemgeo.2025.122759
Primary Topic
Geological and Geochemical Analysis
Type
article
Field-Weighted Citation Impact
0.00

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Subduction and melting of biogenic and ferromanganese sediments as evidenced by sub-Moho granitoids

Marina Seraine, Brian Joy, Derek R. Knaack, Nick M.W. Roberts et al.
Chemical Geology
Geological and Geochemical Analysis
article

Subduction and melting of biogenic and ferromanganese sediments as evidenced by sub-Moho granitoids

Marina Seraine, Brian Joy, Derek R. Knaack, Nick M.W. Roberts, Christopher J. Spencer, Hongyan Li, Gui‐Mei Lu, Tiago Valim Angelo, Ziyi Zhu, Evelyne Leduc, Anna Ren, Sophie Divilek
article en

Abstract

Mantle-hosted granitoids (MHG) from the supra-subduction Samail ophiolite in Oman and the United Arab Emirates exhibit diverse compositions, highlighting variations in petrogenesis and source contributions. Previous isotopic data indicate these MHG originated through the interaction of sediment-derived with basaltic melts from an underthrust oceanic plate within the mantle wedge. The sedimentary contribution was attributed to the partial melting of pelitic to siliceous (bio-siliceous) material atop the subducted plate based on elevated zircon δ 18 O values (∼14–28 ‰). To further evaluate this hypothesis on Samail MHG petrogenesis and source contribution, we present new and compiled radiogenic (Sr-Nd-Hf-Pb) and stable (O-Li-H) isotopes, along with zircon trace element analyses. The variable Sr and Pb isotopic signature support a mixed origin involving altered mafic and sedimentary sources in the formation of the MHG. Negative whole-rock εNd, coupled with elevated δ 7 Li in muscovite suggest the involvement of sedimentary sources and particularly those resembling deep-sea ferromanganese-rich sediments. We propose a new model identifying ferromanganese sediments as a potential source given their widespread distribution across the ocean floor, broad range of δ 18 O (up to 29.5 ‰), slightly positive Hf values, seawater-like δ 7 Li signatures (median of ∼27 ‰), and zircon trace element compositions lacking a signature of monazite co-precipitation, which match the signatures required for the genesis of the Samail MHG. Preservation of oceanic lithosphere in the geological record is limited, and MHG in ophiolites are uncommon. Therefore, the Samail MHG are key examples of crustal materials transported to the mantle, with implications for mantle heterogeneity and arc mantle redox budget. • Isotopes of Samail mantle-hosted granitoids reflect sediment-basalt interaction • Isotopes and trace elements suggest Fe-Mn sediments as a source for mantle-hosted granitoids. • These granitoids serve as key examples of crustal materials recycled into the mantle.

Chemical GeologyVol. 683
British Geological Survey (GB), Chinese Academy of Sciences (CN), Queen's University (CA), Curtin University (AU), Guangzhou Institute of Geochemistry (CN), Monash University (AU)
National Natural Science Foundation of China, Queen's University, Northwest Fisheries Science Center
Openalex Percentile: Top 90%
Geological and Geochemical Analysis
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.