Project Overview for the Pretreatment of HLW by an Electrochemical Denitration and Caustic Generation (EDCGe) System at Hanford - 25518

The Hanford tank waste cleanup mission is the largest environmental liability of the DOE's The WTP facility at Hanford will function to immobilize HLW in vitrified glass, as a suitable waste-form • DF-HLW flowsheet based process has been selected to offer major cost and time savings to the Hanford WTP and stakeholders • DF-HLW flowsheets pose new challenges by bypassing a waste pretreatment facility • Specifically, the feed is rich in nitrites and nitrates, which will produce copious amounts of NOx and NH3 gases at the WTP melter • Processing requirements and complexity of the off-gas treatment process can largely be reduced if NO3 - /NO2 - are removed prior to vitrification

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Published
2025-03-04
DOI
https://doi.org/10.2172/2544972
Primary Topic
Chemical Synthesis and Characterization
Type
article
Field-Weighted Citation Impact
0.00

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article

Project Overview for the Pretreatment of HLW by an Electrochemical Denitration and Caustic Generation (EDCGe) System at Hanford - 25518

Dylan D. Rodene, Margaux Lavenue
Chemical Synthesis and Characterization
article

Project Overview for the Pretreatment of HLW by an Electrochemical Denitration and Caustic Generation (EDCGe) System at Hanford - 25518

Dylan D. Rodene, Margaux Lavenue
article en

Abstract

The Hanford tank waste cleanup mission is the largest environmental liability of the DOE's The WTP facility at Hanford will function to immobilize HLW in vitrified glass, as a suitable waste-form • DF-HLW flowsheet based process has been selected to offer major cost and time savings to the Hanford WTP and stakeholders • DF-HLW flowsheets pose new challenges by bypassing a waste pretreatment facility • Specifically, the feed is rich in nitrites and nitrates, which will produce copious amounts of NOx and NH3 gases at the WTP melter • Processing requirements and complexity of the off-gas treatment process can largely be reduced if NO3 - /NO2 - are removed prior to vitrification

Savannah River National Laboratory (US)
U.S. Department of Energy
Openalex Percentile: Top 92%
Chemical Synthesis and Characterization
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