Research Progress and Prospect of the Bulk Single Crystal Growth of β‐Ga₂O₃: from 1964 to 2024

Abstract β‐Ga 2 O 3 is a promising wide band gap material for power device and solar‐blind photodector applications. With continuous contribution to the crystal growth of β‐Ga 2 O 3 , it is important to conclude the progress of crystal growth techniques and the remaining problems of the materials propel the next generation of the power device industry. The size of single crystals becomes larger, the quality of epitaxial films is gradually improved, and the performance of devices has become better. β‐Ga 2 O 3 is an oxide semiconductor with a large bandgap width of 4.7–4.9 eV and a high breakdown electric field of ≈8 MV cm −1 . In this review, the structure, thermal properties, optical properties, and electronic properties of β‐Ga 2 O 3 are introduced first. Then, the growth methods of bulk β‐Ga 2 O 3 single crystals are introduced, including the Verneuil method, Czochralski (CZ) method, optical‐floating zone (OFZ) method, edge‐defined film‐fed growth (EFG) method, vertical Bridgman (VB) method, casting method, and the oxide crystal growth from cold crucible (OCCC) method. Crystal growth mechanisms and their respective advantages and disadvantages are discussed. The effects of doping elements on the crystal growth have been highlighted in each method. Finally, the prospect of the growth of large β‐Ga 2 O 3 single crystals is discussed.