Electrochemical sensor for detecting roxarsone in animal-derived foods using MXene and silver telluride
Detecting harmful feed additives in animal-derived foods is essential due to potential health and environmental risks. Given its toxicity, Roxarsone, a common organoarsenic compound, requires sensitive detection methods. This study introduces an electrochemical sensor using a glassy carbon electrode modified with 2D MXene (Ti<sub>3</sub>C<sub>2</sub>Tₓ) layered with silver telluride (Ag<sub>2</sub>Te). Characterization through XRD, FT-IR, and XPS confirmed the sensor's composition. Electrochemical assessments using cyclic voltammetry and differential pulse voltammetry showed notable electron transfer and catalytic efficiency improvements. The sensor exhibited a broad detection range for roxarsone (0.03-2310 μM) with an ultra-low detection limit (0.32 nM) and demonstrated excellent reproducibility (RSD < 3 %), stability, and selectivity. Real sample analysis in meat products confirmed its practical application, achieving high recovery rates. This work offers a robust approach for roxarsone detection, employing MXene and Ag<sub>2</sub>Te's synergistic properties to enhance food safety and environmental monitoring.
Authors
- Yen‐Yi Lee
- Sakthivel Kogularasu (ORCID: https://orcid.org/0000-0002-4606-3846)
- Mani Govindasamy (ORCID: https://orcid.org/0000-0001-6701-6507)
- M. Perumal (ORCID: https://orcid.org/0000-0001-9327-0429)
- Guo‐Ping Chang‐Chien
- Yung‐Lung Chen
Institutions
- Ming Chi University of Technology (TW)
- Chang Gung University (TW)
- Kaohsiung Chang Gung Memorial Hospital (TW)
- Cheng Shiu University (TW)
Publication Details
- Journal
- Food Chemistry
- Published
- 2025-04-02
- DOI
- https://doi.org/10.1016/j.foodchem.2025.144168
- Citations
- 15
- Primary Topic
- Advanced biosensing and bioanalysis techniques
- Type
- article
- Field-Weighted Citation Impact
- 12.09
Funders
- Chang Gung Medical Foundation
- Ming Chi University of Technology