Energy State Estimation for Series-Connected Battery Packs Based on Online Curve Construction of Pack Comprehensive OCV

Accurate estimation of the state of energy (SOE) in lithium-ion batteries is crucial for determining the output power and driving range of electric vehicles. However, in series-connected battery packs, inconsistencies among individual cells pose significant challenges for precise SOE estimation. This issue is particularly pronounced for lithium iron phosphate (LFP) batteries. Their relatively flat open-circuit voltage (OCV) curve makes the classic method of directly weighting the SOE of representative cells—commonly used for ternary batteries—ineffective. This is because the traditional method relies heavily on a linear relationship between the SOE and the voltage, which is not present in LFP batteries. To address this challenge, a novel SOE estimation approach based on the online construction of the battery pack’s comprehensive OCV curve is proposed in this paper. In this new approach, the weighting of representative cells shifts from a result-oriented mode to a key-parameter-oriented mode. By adopting this mode, the whole pack’s comprehensive OCV can be obtained training free and the pack’s SOE can be estimated online within an equivalent circuit model framework. The experimental results demonstrate that the proposed method effectively controls the SOE estimation error within 3% for series battery packs composed of cells with varying degrees of aging.