Impact of anionic co-ligands on nuclearity and single-molecule magnetism in a {CoIII2Dy<sup>III</sup>} trimeric and two {CoIII2DyIII2} tetrameric complexes
R - and S -isomers of H 3 L yield tri- and tetranuclear Co III –Dy III complexes showing zero-field slow relaxation, one of which shows the highest U eff (200 K). Ab initio studies reveal anisotropy and relaxation pathways, advancing Co III –Dy III -based SMMs.
Authors
- Daniel Aravena (ORCID: https://orcid.org/0000-0003-3140-4852)
- Zvonko Jagličić (ORCID: https://orcid.org/0000-0002-4118-9677)
- Anangamohan Panja (ORCID: https://orcid.org/0000-0002-6864-0501)
- Narayan Ch. Jana (ORCID: https://orcid.org/0000-0002-2849-5784)
- Rakhi Nandy
- Scarlette Contesso
Institutions
- Universidad de Santiago de Chile (CL)
- University of Ljubljana (SI)
- Gokhale Institute of Politics and Economics (IN)
- Institute of Mathematics, Physics, and Mechanics (SI)
- Panskura Banamali College
Publication Details
- Journal
- New Journal of Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5nj00766f
- Citations
- 3
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 1.28