Tuning the Catalytic Activity of MoS2−x−NbSx Heterostructure Nanosheets for Bifunctional Acidic Water Splitting
Developing durable electrocatalysts with high activity for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) in acidic media is critically important for clean power production. In this study, MoS<sub>2-x</sub>-NbS<sub>x</sub> heterostructure nanosheets are synthesized from a solid-state reaction method followed by liquid phase exfoliation, and their catalytic performance is optimized. The MoS<sub>2-x</sub>-NbS<sub>x</sub> heterostructure nanosheets with optimal precursors ratio exhibit promising attributes for applications in the HER and OER compared to pristine MoS<sub>2</sub> and Nb under the same conditions. The MoS<sub>2-x</sub>-NbS<sub>x</sub> heterostructure nanosheets catalyst on glassy carbon electrodes shows the minimum overpotential of 159 mV for HER and 295 mV for OER at a current density of 10 mA cm<sup>-2</sup> in 0.5 m H<sub>2</sub>SO<sub>4</sub>. This research offers valuable insights into the fabrication of heterostructure nanosheets and evaluates their potential as effective electrocatalysts for water splitting compared with pristine 2D materials in an acid environment.
Authors
- Muhammad Tahir (ORCID: https://orcid.org/0000-0002-6369-5714)
- Liang Ming He (ORCID: https://orcid.org/0000-0002-7402-9194)
- Wan Nadilah Wan Ahmad (ORCID: https://orcid.org/0009-0004-5947-7740)
- Longbing Qu (ORCID: https://orcid.org/0000-0001-9725-2738)
- Jun Dai (ORCID: https://orcid.org/0000-0002-6726-1198)
- Iqra Shahbaz (ORCID: https://orcid.org/0009-0006-9184-2802)
- Fazal Ul Nisa
- Zeyu Ma (ORCID: https://orcid.org/0000-0002-3823-502X)
- Arif Ullah Khan (ORCID: https://orcid.org/0000-0002-0528-1871)
- Mizna Naseem
Institutions
- Beijing Institute of Technology (CN)
- The University of Melbourne (AU)
- Chinese Academy of Sciences (CN)
- Sichuan University (CN)
- West China Hospital of Sichuan University (CN)
- Beijing National Laboratory for Molecular Sciences (CN)
- Yibin University (CN)
Publication Details
- Journal
- Small
- Published
- 2025-04-01
- DOI
- https://doi.org/10.1002/smll.202501464
- Citations
- 17
- Primary Topic
- Electrocatalysts for Energy Conversion
- Type
- article
- Field-Weighted Citation Impact
- 6.18
Funders
- National Natural Science Foundation of China
- Fundamental Research Funds for the Central Universities