Taming a silent killer: uncovering the role of excited states and uncoordinated selenium moieties in the CO photorelease mechanism of manganese( <scp>i</scp> ) carbonyl compounds
This study investigates CO photorelease using experimental and computational approaches, with organoselenium ligands featuring a free selenium moiety capable of stabilizing intermediates in situ .
Authors
- Adaı́lton J. Bortoluzzi
- Daniele C. Durigon (ORCID: https://orcid.org/0000-0002-1955-5546)
- Ebbe Nordlander (ORCID: https://orcid.org/0000-0001-9575-4929)
- Rosely A. Peralta (ORCID: https://orcid.org/0000-0002-6417-2683)
- Vinícius A. Glitz (ORCID: https://orcid.org/0000-0001-7245-2522)
- Giovanni F. Caramori (ORCID: https://orcid.org/0000-0002-6455-7831)
- Antônio L. Braga (ORCID: https://orcid.org/0000-0001-9903-6764)
- André L. Amorim (ORCID: https://orcid.org/0000-0002-1566-1843)
- Yara S. Ricken
Institutions
- Lund University (SE)
- Universidade Federal de Santa Catarina (BR)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00162e
- Citations
- 5
- Primary Topic
- CO2 Reduction Techniques and Catalysts
- Type
- article
- Field-Weighted Citation Impact
- 1.82