A Similarity Theory-Based Study on Natural Convection Condensation Boundary Layer Characteristics of Vertical Walls

To address the challenge of heat transfer enhancement in the condensation of steam with non-condensable gases on a vertical wall under natural convection conditions, an improved boundary layer model with coupled multi-physics field was proposed in this paper, and traditional theoretical limitations were broken through by innovations. The particle swarm optimization algorithm was first introduced into the solution of the condensation boundary layer, and the convergence difficulty in the laminar–turbulent transition region under infinite boundary conditions was overcome. A coupled momentum–energy–mass equation system that simultaneously considered temperature–concentration dual-driven gravity terms and liquid film drag–suction dual effects was established, and higher computational efficiency and accuracy were achieved. A new mechanism where the concentration boundary layer dominated heat transfer resistance under the coupled action of the Prandtl number (Pr) and Schmidt number (Sc) was revealed. Experimental validation demonstrated that a prediction error of less than 5% was exhibited by the model under typical operating conditions of passive containment cooling systems (pressures of 1.5–4.5 atm and subcooling temperatures of 14–36 °C), and a theoretical tool for high-precision condensation heat transfer design was provided.