Electrochemical Cross‐Coupling Reactions

Abstract The last few decades have seen an increase in the significance of green and sustainable synthetic processes for the synthesis of fine chemicals in an attempt to minimize the consumption of fossil fuels and other limited resources. Electrical power offers a cost‐effective, eco‐friendly, and intrinsically safe alternative to conventional reagents for creating new synthetic pathways. In this regard, in recent years, there has been a rapid advancement in the field of electrochemically cross‐coupling reactions. Therefore, this review aims to give a thorough overview of synthetic approaches concentrating on processes that bring new conceptual advancements and the present state of mechanistic understanding, as well as attempts to provide an overview of the area from the past two years (From March 2023 to Jan 2025). Sections are divided according to the kind of bond being constructed, such as C−C bond formation, C−X (hetero), and X−Y (hetero–hetero) bond formation. This instructional review aims to advance the fields of electrochemistry, radical chemistry, and oxidative/reductive cross‐coupling reactions.