Unraveling the divergent mode of Cu- or Zn-assisted radical addition of imines: a mechanistic perspective on Lewis acidic metal-induced enantioselectivity
As widely used Lewis acidic metals, Cu and Zn possess distinct redox properties and coordination modes, potentially leading to different radical addition mechanisms.
Authors
- Ruopeng Bai (ORCID: https://orcid.org/0000-0002-1097-8526)
- Dongmin Fu
- Xiaokang Guo (ORCID: https://orcid.org/0009-0003-1722-7893)
- Yu Lan (ORCID: https://orcid.org/0009-0001-0659-7587)
- Jiang Wu (ORCID: https://orcid.org/0000-0003-1929-3328)
- Kai Yang (ORCID: https://orcid.org/0000-0003-2975-1767)
- Tao Zhang (ORCID: https://orcid.org/0009-0002-1668-0453)
Institutions
- Chongqing University (CN)
- Zhengzhou University (CN)
- Henan Academy of Sciences (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00530b
- Citations
- 3
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 2.81