Synthesis of 4-Nitroisoxazole-Based Energetic Materials
A set of novel biheterocyclic energetic materials incorporating the 4-nitroisoxazole scaffold was synthesized. Thus, prepared species demonstrated excellent thermal stability (181-244 °C), good densities (1.71-1.74 g·cm<sup>-3</sup>), and detonation velocities (7.6-8.3 km s<sup>-1</sup>), while retaining insensitivity to friction. To the best of our knowledge, this is the first example of an incorporation of the 4-nitroisoxazole scaffold into the structure of high-energy materials.
Authors
- Алла Н. Пивкина (ORCID: https://orcid.org/0000-0002-3779-2449)
- Д. Б. Виноградов (ORCID: https://orcid.org/0000-0002-9235-6113)
- Alexey A. Konnov (ORCID: https://orcid.org/0000-0001-9432-0088)
- A. Nazarova (ORCID: https://orcid.org/0000-0003-1724-5322)
- Леонид Л. Ферштат (ORCID: https://orcid.org/0000-0002-0203-1025)
- Anton D. Lisyutkin
Institutions
- National Research University Higher School of Economics (RU)
- Russian Academy of Sciences (RU)
- Semenov Institute of Chemical Physics (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Organic Letters
- Published
- 2025-04-01
- DOI
- https://doi.org/10.1021/acs.orglett.5c01074
- Citations
- 8
- Primary Topic
- Energetic Materials and Combustion
- Type
- article
- Field-Weighted Citation Impact
- 6.91
Funders
- Russian Science Foundation