Addition of Diols to 2-Methylidene-1,4-dioxaspiro[4.5]decane
A procedure has been developed for electrophilic addition of 1,2-, 1,3-, and 1,4-diols to 4-methylidene-1,3-dioxolane using trifluoroacetic acid as catalyst. Conditions have been found for the predominant formation of monoadducts in 31–70% yield.
Authors
- Yu. G. Borisova (ORCID: https://orcid.org/0000-0001-6452-9454)
- А. А. Голованов (ORCID: https://orcid.org/0000-0001-7133-3070)
- S. S. Zlotskii (ORCID: https://orcid.org/0000-0001-6365-5010)
- S. A. Sokov (ORCID: https://orcid.org/0000-0002-0639-0455)
- Г. З. Раскильдина (ORCID: https://orcid.org/0000-0001-9770-5434)
Institutions
- Ufa State Petroleum Technological University (RU)
Publication Details
- Journal
- Russian Journal of Organic Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1134/s1070428024602486
- Primary Topic
- Chemical Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 0.00