Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer

Catalytic transfer hydrodechlorination of chlorobenzene using 2-propanol as the hydrogen donor and a mixed Ni-Mo sulfide phase deposited on alumina as the catalyst is studied at temperatures 250-300 °C. When triethylamine is applied as the HCl neutralizer, benzene is the only product, whereas with inorganic bases (iso)propylbenzenes are also formed.

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Publication Details

Journal
Mendeleev Communications
Published
2025-01-01
DOI
https://doi.org/10.71267/mencom.7630
Citations
2
Primary Topic
Nanomaterials for catalytic reactions
Type
article
Field-Weighted Citation Impact
1.87

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article

Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer

В. П. Пахарукова, I. V. Kozhevnikov, Alexander S. Romanov, Anna A. Salomatina et al.
2 citations
Mendeleev Communications
Nanomaterials for catalytic reactions
1.87
article

Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer

В. П. Пахарукова, I. V. Kozhevnikov, Alexander S. Romanov, Anna A. Salomatina, Alexey A. Philippov, A. M. Chibiryaev, Oleg N. Martyanov, N. S. Nesterov, О. В. Климов
article en
2 citations

Abstract

Catalytic transfer hydrodechlorination of chlorobenzene using 2-propanol as the hydrogen donor and a mixed Ni-Mo sulfide phase deposited on alumina as the catalyst is studied at temperatures 250-300 °C. When triethylamine is applied as the HCl neutralizer, benzene is the only product, whereas with inorganic bases (iso)propylbenzenes are also formed.

Mendeleev CommunicationsVol. 35(3)
Boreskov Institute of Catalysis (RU)
Russian Science Foundation
Openalex Percentile: Top 17%
Nanomaterials for catalytic reactions
1.87
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Transfer hydrodechlorination of chlorobenzene over Ni--Mo sulfide system and effect of HCl neutralizer — В. П. Пахарукова, I. V. Kozhevnikov, et al. · Mendeleev Communications (2025) | TGRS Research Map | TGRS