Facile, efficient and green phthalimide synthesis in supercritical carbon dioxide
The reactions between phthalic anhydrides and primary amines in supercritical CO<sub>2</sub> (80-110 bar) to afford the corresponding phthalimides proceed at temperatures of 120-130 °C (aliphatic amines) or 260-275 °C (aromatic amines). The developed procedure fully complies with the principles of green chemistry and allows one to obtain target phthalimides in 65-85
Authors
- Dmitry A. Guk (ORCID: https://orcid.org/0000-0002-5674-8654)
- D. A. Lemenovśkii (ORCID: https://orcid.org/0000-0001-7380-3136)
- Elena Kimovna Beloglazkina (ORCID: https://orcid.org/0000-0001-6796-8241)
- Vadim Filatov (ORCID: https://orcid.org/0000-0003-2651-0941)
- Dmitrii A. Iuzabchuk (ORCID: https://orcid.org/0000-0001-9939-7762)
Institutions
- Russian Academy of Sciences (RU)
- Lomonosov Moscow State University (RU)
- A.V. Topchiev Institute of Petrochemical Synthesis (RU)
Publication Details
- Journal
- Mendeleev Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.71267/mencom.7646
- Primary Topic
- Innovative Microfluidic and Catalytic Techniques Innovation
- Type
- article
- Field-Weighted Citation Impact
- 0.00