Unusual formation of 4-diazo-3-nitriminopyrazoles upon acid nitration of pyrazolo[3,4-<em>d</em>][1,2,3]triazoles
Nitration of 6-R-4-phenylpyrazolo[3,4-<em>d</em>][1,2,3]triazoles at the phenyl substituent is accompanied by the triazole ring opening to give new 3-R-4-diazo-1-(di)nitrophenylpyrazole- 5-nitrimines. Chemical and physicochemical properties of the prepared compounds are reported.
Authors
- Igor L. Dalinger (ORCID: https://orcid.org/0000-0003-4100-2611)
- Алла Н. Пивкина (ORCID: https://orcid.org/0000-0002-3779-2449)
- Kyrill Yu. Suponitsky (ORCID: https://orcid.org/0000-0003-0617-0118)
- T. E. Khoranyan
- Alexandr V. Kormanov (ORCID: https://orcid.org/0000-0003-1607-6969)
Institutions
- Semenov Institute of Chemical Physics (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Mendeleev Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.71267/mencom.7628
- Primary Topic
- Synthesis and Biological Evaluation
- Type
- article
- Field-Weighted Citation Impact
- 0.00