Oxidation of toluene with N<sub>2</sub>O on ZSM-5 zeolite under supercritical conditions
The direct oxidation of toluene to cresols with nitrous oxide as the oxidant was carried out over a ZSM-5 zeolite catalyst under gaseous and supercritical conditions (395 °C and 0.5, 7, 12 MPa; 420 °C and 15 MPa). The supercritical oxidation is characterized by a significantly greater productivity as compared to the gas-phase process. Successful <em>in situ </em>regeneration of the deactivated catalyst during the transition from the gas-phase to the supercritical process has been demonstrated.
Authors
- Alexander L. Kustov (ORCID: https://orcid.org/0000-0003-0869-8784)
- Vladimir L. Zholobenko (ORCID: https://orcid.org/0000-0002-6024-0503)
- Igor I. Mishanin (ORCID: https://orcid.org/0000-0002-6063-6428)
- Т. В. Богдан (ORCID: https://orcid.org/0000-0002-1078-1141)
- В. И. Богдан (ORCID: https://orcid.org/0000-0001-9716-1748)
- Sergey Eduardovich Bogorodskiy
- N. V. Mashchenko (ORCID: https://orcid.org/0000-0002-2200-2221)
- А. Е. Коклин (ORCID: https://orcid.org/0000-0002-1304-2408)
Institutions
- Lomonosov Moscow State University (RU)
- N.D. Zelinsky Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Mendeleev Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.71267/mencom.7626
- Citations
- 1
- Primary Topic
- Catalytic Processes in Materials Science
- Type
- article
- Field-Weighted Citation Impact
- 0.52
Funders
- Ministry of Education and Science of the Russian Federation