Synthesis of perfluorobiphenyl tetracarboxylic acids <em>via</em> the CuCl<sub>2</sub>-assisted homocoupling of organozinc reagents
New organozinc reagents were obtained from ethyl esters of tetrafluorophenylene dicarboxylic acids in the reaction with Zn and SnCl<sub>2</sub> in DMF. Tetraethyl perfluorobiphenyl tetracarboxylates were synthesized from these organozinc reagents under the action of CuCl<sub>2</sub> and then were hydrolyzed into perfluorobiphenyl tetracarboxylic acids.
Authors
- T. V. Mezhenkova (ORCID: https://orcid.org/0000-0001-9936-0900)
- Vladislav V. Komarov (ORCID: https://orcid.org/0000-0001-6079-3039)
- V. Е. Platonov
- A. S. Vinogradov (ORCID: https://orcid.org/0000-0002-7910-9062)
Institutions
- Novosibirsk Institute of Organic Chemistry (RU)
Publication Details
- Journal
- Mendeleev Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.71267/mencom.7682
- Primary Topic
- Fluorine in Organic Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Russian Science Foundation