Cantilever-Enhanced Photoacoustic Spectroscopy: Simultaneous Demodulation of Resonant and Nonresonant Signals for the Measurement of Dual SF<sub>6</sub> Decomposition Components

Photoacoustic spectroscopy (PAS) gas sensing systems are generally classified into resonant and nonresonant types. However, it remains unclear whether signals at both resonant and nonresonant frequencies can be demodulated by one demodulation channel and one pass cell to achieve the simultaneous detection of two target molecules. In this study, a cantilever-enhanced photoacoustic (PA) gas detection system was utilized to measure H<sub>2</sub>S and CO<sub>2</sub>, both of which have been identified as typical fault gases in SF<sub>6</sub> gas-insulated electrical equipment. The vibration modes of the cantilever beam at its first resonant and nonresonant frequencies were simulated and analyzed. Utilizing a laser interferometer, the vibration signals of a cantilever beam were measured. The results confirm that the resonant and nonresonant components of the vibration signal can be demodulated simultaneously. Gas detection experiments were conducted using a cantilever beam-based PAS gas sensing unit. Measurements in the ternary gas mixtures demonstrated the feasibility of simultaneously detecting H<sub>2</sub>S and CO<sub>2</sub> by extracting components at 34 and 349 Hz. The PA signals exhibited a strong linear relationship with the gas concentrations, and the detection limits of H<sub>2</sub>S and CO<sub>2</sub> are 2.55 and 84.69 ppm, respectively.

Authors

Institutions

Publication Details

Journal
Analytical Chemistry
Published
2025-03-31
DOI
https://doi.org/10.1021/acs.analchem.4c03543
Citations
2
Primary Topic
Spectroscopy and Laser Applications
Type
article
Field-Weighted Citation Impact
1.51

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Cantilever-Enhanced Photoacoustic Spectroscopy: Simultaneous Demodulation of Resonant and Nonresonant Signals for the Measurement of Dual SF6 Decomposition Components

Hongtu Cheng, Jie Feng, Zhi Fang, Yang Shen
2 citations
Analytical Chemistry
Spectroscopy and Laser Applications
1.51
article

Cantilever-Enhanced Photoacoustic Spectroscopy: Simultaneous Demodulation of Resonant and Nonresonant Signals for the Measurement of Dual SF6 Decomposition Components

Hongtu Cheng, Jie Feng, Zhi Fang, Yang Shen
article en
2 citations

Abstract

Photoacoustic spectroscopy (PAS) gas sensing systems are generally classified into resonant and nonresonant types. However, it remains unclear whether signals at both resonant and nonresonant frequencies can be demodulated by one demodulation channel and one pass cell to achieve the simultaneous detection of two target molecules. In this study, a cantilever-enhanced photoacoustic (PA) gas detection system was utilized to measure H<sub>2</sub>S and CO<sub>2</sub>, both of which have been identified as typical fault gases in SF<sub>6</sub> gas-insulated electrical equipment. The vibration modes of the cantilever beam at its first resonant and nonresonant frequencies were simulated and analyzed. Utilizing a laser interferometer, the vibration signals of a cantilever beam were measured. The results confirm that the resonant and nonresonant components of the vibration signal can be demodulated simultaneously. Gas detection experiments were conducted using a cantilever beam-based PAS gas sensing unit. Measurements in the ternary gas mixtures demonstrated the feasibility of simultaneously detecting H<sub>2</sub>S and CO<sub>2</sub> by extracting components at 34 and 349 Hz. The PA signals exhibited a strong linear relationship with the gas concentrations, and the detection limits of H<sub>2</sub>S and CO<sub>2</sub> are 2.55 and 84.69 ppm, respectively.

Analytical ChemistryVol. 97(14)
Nanjing Tech University (CN), Wuhan University (CN)
China Postdoctoral Science Foundation
Openalex Percentile: Top 20%
Spectroscopy and Laser Applications
1.51
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.