Kinetic resolution of binols and biphenols <i>via</i> dehydrogenative coupling with hydrosilanes catalyzed by chiral FLPs
A kinetic resolution of binols and biphenols has been realized <i>via</i> dehydrogenative coupling with hydrosilanes catalyzed by a frustrated Lewis pair of chiral borane and chiral phosphine. A variety of axially chiral siloxanes, along with the corresponding optically active binols and biphenols, were obtained in good yields with moderate to high enantioselectivities.
Authors
- Xiangqing Feng (ORCID: https://orcid.org/0000-0003-1739-925X)
- Zhibin Zhang (ORCID: https://orcid.org/0000-0003-2090-7999)
- Haifeng Du (ORCID: https://orcid.org/0000-0003-0122-3735)
Institutions
- Chinese Academy of Sciences (CN)
- Beijing National Laboratory for Molecular Sciences (CN)
- Institute of Chemistry (CN)
- University of Chinese Academy of Sciences (CN)
Publication Details
- Journal
- Organic & Biomolecular Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ob00347d
- Citations
- 1
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.94