An experimental data library for the full CsPb(Cl<sub><i>x</i></sub>Br<sub>1−<i>x</i></sub>)<sub>3</sub> compositional series
A complete series of CsPb(Cl<sub><i>x</i></sub>Br<sub>1-<i>x</i></sub>)<sub>3</sub> mixed-halide perovskites with <i>x</i> = 0-1 in small steps is reported, and their structural and optical properties characterised. A comparison of synthetic approaches shows that mechanosynthesis yields the most robust data across the compositions, avoiding solvent inclusion or miscibility gaps. The resulting data library, including some hitherto unreported compositions, can serve as a benchmark for future computational modelling.
Authors
- Sascha Feldmann (ORCID: https://orcid.org/0000-0002-6583-5354)
- Michael A. Hayward (ORCID: https://orcid.org/0000-0002-6248-2063)
- Antti‐Pekka M. Reponen (ORCID: https://orcid.org/0000-0002-2076-410X)
- Volker L. Deringer (ORCID: https://orcid.org/0000-0001-6873-0278)
- Zachary A. VanOrman (ORCID: https://orcid.org/0000-0002-7773-012X)
- K.K. Banger
- Kinga O. Mastej
- Bodoo Batnaran
Institutions
- Harvard University (US)
- University of Oxford (GB)
- École Polytechnique Fédérale de Lausanne (CH)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00735f
- Citations
- 3
- Primary Topic
- Perovskite Materials and Applications
- Type
- article
- Field-Weighted Citation Impact
- 2.19
Funders
- National Science Foundation
- École Polytechnique Fédérale de Lausanne
- Rowland Institute at Harvard
- Engineering and Physical Sciences Research Council