Palladium-immobilization on KIT-6 mesoporous silica magnetite nanoparticles as a stable nanocatalyst for cross-coupling and homo-coupling reactions

KIT-6 mesoporous silica-coated magnetite nanoparticles are organized large-pore nanoparticles that facilitate an environmentally friendly procedure for Ullmann, Suzuki-Miyaura, and Stille reactions. Various techniques, such as FTIR, SEM, TGA, VSM, XRD, BET, and AAS, were used to investigate and identify the synthesized Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>@KIT-6@IS-Pd<sup>0</sup> catalyst. The magnetite nanoparticles could be easily separated from the reaction mixture simply by magnetic decantation, and they could be reused for several consecutive runs without seeing a significant decrease in catalytic activity.

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Publication Details

Journal
Nanoscale Advances
Published
2025-01-01
DOI
https://doi.org/10.1039/d5na00058k
Citations
3
Primary Topic
Catalytic Cross-Coupling Reactions
Type
article
Field-Weighted Citation Impact
2.81
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article

Palladium-immobilization on KIT-6 mesoporous silica magnetite nanoparticles as a stable nanocatalyst for cross-coupling and homo-coupling reactions

Zahra Moradi, Mostafa Koolivand, Mohsen Nikoorazm, Arash Ghorbani‐Choghamarani
3 citations
Nanoscale Advances
Catalytic Cross-Coupling Reactions
2.81
article

Palladium-immobilization on KIT-6 mesoporous silica magnetite nanoparticles as a stable nanocatalyst for cross-coupling and homo-coupling reactions

Zahra Moradi, Mostafa Koolivand, Mohsen Nikoorazm, Arash Ghorbani‐Choghamarani
article en
3 citations

Abstract

KIT-6 mesoporous silica-coated magnetite nanoparticles are organized large-pore nanoparticles that facilitate an environmentally friendly procedure for Ullmann, Suzuki-Miyaura, and Stille reactions. Various techniques, such as FTIR, SEM, TGA, VSM, XRD, BET, and AAS, were used to investigate and identify the synthesized Fe<sub>3</sub>O<sub>4</sub>@SiO<sub>2</sub>@KIT-6@IS-Pd<sup>0</sup> catalyst. The magnetite nanoparticles could be easily separated from the reaction mixture simply by magnetic decantation, and they could be reused for several consecutive runs without seeing a significant decrease in catalytic activity.

Nanoscale AdvancesVol. 7(10)
Bu-Ali Sina University (IR), Ilam University (IR)
Life in Land
Openalex Percentile: Top 11%
Catalytic Cross-Coupling Reactions
2.81
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Palladium-immobilization on KIT-6 mesoporous silica magnetite nanoparticles as a stable nanocatalyst for cross-coupling and homo-coupling reactions — Zahra Moradi, Mostafa Koolivand, et al. · Nanoscale Advances (2025) | TGRS Research Map | TGRS