Disentangling edge and bulk spin-to-charge interconversion in MoS2 monolayer flakes

Semiconductor transition metal dichalcogenides are an archetype for spintronic devices due to their spin-to-charge interconversion mechanisms. However, the exact microscopic origin of this interconversion is not yet determined. In our study, we investigated light-induced spin pumping in YIG/MoS₂ heterostructures. Our findings revealed that the MoS₂ monolayer microsized flakes contribute to spin current injection through two distinct mechanisms: metallic edge states and semiconductor area states. The competition between these mechanisms, influenced by the flake size, leads to different behaviors of spin-pumping. Our calculations of the local density of states, by means of density functional theory, of a flake show that light-driven spin current injection can be controlled based on the intensity of light with a suitable wavelength. We demonstrate that a lightdriven spin current injection can enhance up to very high values, attenuate, or even switch on/off the spin-to-charge interconversion. These results hold promise for developing low energy-consuming opto-spintronic device applications.