A DFT investigation of the mechanism of photoinduced radical borylation of alkyl bromides: elucidation of base-mediated photoinduced SET and S<sub>N</sub>2 processes
DFT calculations indicate that in the photoinduced radical borylation of alkyl bromides, the generation of alkyl radicals mainly results from the two successive photoinduced SET processes alongside S N 2/photoinduced SET.
Authors
- Guisheng Zhang (ORCID: https://orcid.org/0000-0001-9880-950X)
- Nana Ma (ORCID: https://orcid.org/0000-0003-3225-9554)
- Danna Zhao (ORCID: https://orcid.org/0000-0002-4997-3028)
- Shujun Li (ORCID: https://orcid.org/0000-0002-6230-4806)
- Qiongjin Wang
- B.Y. Duan (ORCID: https://orcid.org/0009-0000-3048-4796)
Institutions
- Henan Normal University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00048c
- Citations
- 2
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.87