Palladium-catalysed asymmetric regioselective hydroamination of dienoates
An asymmetric formal 1,4-Michael addition-type reaction between δ-aryl-substituted dienoates and pyrazoles has been developed, through a Pd 0 π-Lewis base mediated protonation and allylic amination process.
Authors
- Shuo Li (ORCID: https://orcid.org/0009-0001-1544-2608)
- Wei Du (ORCID: https://orcid.org/0000-0003-4162-1471)
- Qin Ouyang (ORCID: https://orcid.org/0000-0002-1161-5102)
- Xiang Qin (ORCID: https://orcid.org/0000-0002-1998-595X)
- Lei Zhu (ORCID: https://orcid.org/0000-0003-1685-7968)
- Ying‐Chun Chen (ORCID: https://orcid.org/0000-0003-1902-0979)
- Bao-Xin Liu
Institutions
- Army Medical University (CN)
- Sichuan University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00402k
- Citations
- 5
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 4.68