Kovacs-like memory effect in a sheared colloidal glass: role of non-affine flows

Memory effect reflects a system's ability to encode, retain and retrieve information about its past. Such effects are essentially an out-of-equilibrium phenomenon providing insight into the complex structural and dynamical behavior of the system. Kovacs effect is one such memory effect that is traditionally associated with thermal history. Although studies on the Kovacs-like memory effect have been extended to mechanical perturbations such as compression-decompression, whether such effects can also be observed under volume-conserving perturbations like shear, remains unclear. Combining experiments, simulations and linear response theory we demonstrate Kovacs-like memory effect in a sheared colloidal glass. Moreover, we explore the influence of non-linear perturbations and establish a correlation between the deviation from linear response prediction and microscopic non-affine flows generated due to such large deformations in affecting the memory effect. Our study not only extends Kovacs-like memory effect in the domain of volume-conserving mechanical perturbations, it also highlights the importance of the nature of underlying microscopic flows in controlling the bulk stress relaxation, affecting the Kovacs-like memory effect in amorphous materials.

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Publication Details

Journal
Soft Matter
Published
2025-01-01
DOI
https://doi.org/10.1039/d4sm01514b
Citations
1
Primary Topic
Pickering emulsions and particle stabilization
Type
article
Field-Weighted Citation Impact
0.52

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article

Kovacs-like memory effect in a sheared colloidal glass: role of non-affine flows

Sayantan Majumdar, Abhishek Ghadai, Maitri Mandal, Rituparno Mandal
1 citations
Soft Matter
Pickering emulsions and particle stabilization
0.52
article

Kovacs-like memory effect in a sheared colloidal glass: role of non-affine flows

Sayantan Majumdar, Abhishek Ghadai, Maitri Mandal, Rituparno Mandal
article en
1 citations

Abstract

Memory effect reflects a system's ability to encode, retain and retrieve information about its past. Such effects are essentially an out-of-equilibrium phenomenon providing insight into the complex structural and dynamical behavior of the system. Kovacs effect is one such memory effect that is traditionally associated with thermal history. Although studies on the Kovacs-like memory effect have been extended to mechanical perturbations such as compression-decompression, whether such effects can also be observed under volume-conserving perturbations like shear, remains unclear. Combining experiments, simulations and linear response theory we demonstrate Kovacs-like memory effect in a sheared colloidal glass. Moreover, we explore the influence of non-linear perturbations and establish a correlation between the deviation from linear response prediction and microscopic non-affine flows generated due to such large deformations in affecting the memory effect. Our study not only extends Kovacs-like memory effect in the domain of volume-conserving mechanical perturbations, it also highlights the importance of the nature of underlying microscopic flows in controlling the bulk stress relaxation, affecting the Kovacs-like memory effect in amorphous materials.

Soft MatterVol. 21(15)
Raman Research Institute (IN), University of Chicago (US)
Science and Engineering Research Board
Openalex Percentile: Top 41%
Pickering emulsions and particle stabilization
0.52
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Kovacs-like memory effect in a sheared colloidal glass: role of non-affine flows — Sayantan Majumdar, Abhishek Ghadai, et al. · Soft Matter (2025) | TGRS Research Map | TGRS