A Post-Synthetic Modification Approach to Expand MIL-101-NH2 Functionalization
Considering the importance of organic functionalization of MOFs, we here report a simple, tunable and efficient one-step post-modification procedure for introducing amino and carboxylic groups into the mesoporous metal–organic framework Al- and Cr-MIL-101-NH2 based on its reaction with alkyl bromides. This procedure allows also access to polyfunctionalized MIL-101 decorated with both carboxylic and primary amino groups. Other chemical functions, such as alcohols and alkynes, were also successfully introduced by this method.
Authors
- Christophe Laurent (ORCID: https://orcid.org/0000-0002-2702-1683)
- Isabelle Fabing (ORCID: https://orcid.org/0000-0002-8502-3986)
- Christian Lherbet (ORCID: https://orcid.org/0000-0001-5427-5040)
- Pascal Hoffmann (ORCID: https://orcid.org/0000-0002-8707-3928)
- Marie‐Claire Barthélémy
- Alain Vigroux (ORCID: https://orcid.org/0000-0002-7542-0320)
Institutions
- Centre National de la Recherche Scientifique (FR)
- Université Fédérale de Toulouse Midi-Pyrénées (FR)
- Centre Interuniversitaire de Recherche et d’Ingénierie des Matériaux (FR)
- Molécules d'Intérêt Biologique (FR)
Publication Details
- Journal
- Chemistry
- Published
- 2025-03-28
- DOI
- https://doi.org/10.3390/chemistry7020048
- Citations
- 3
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.61
Funders
- Centre National de la Recherche Scientifique