Catalytic (5 + 1) cycloaddition of diazooxindoles with imidazolidines to access novel piperazine-spirooxindole frameworks

A rhodium or copper catalyzed (5 + 1) cycloaddition of diazooxindoles with imidazolidines is reported, offering a series of structurally novel piperazine-spirooxindoles. The asymmetric version has also been realized under Cu( ii )/SaBOX system.

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Publication Details

Journal
Organic Chemistry Frontiers
Published
2025-01-01
DOI
https://doi.org/10.1039/d5qo00361j
Citations
7
Primary Topic
Cyclopropane Reaction Mechanisms
Type
article
Field-Weighted Citation Impact
6.55
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article

Catalytic (5 + 1) cycloaddition of diazooxindoles with imidazolidines to access novel piperazine-spirooxindole frameworks

Shiyong Peng, Wendi Xu, Yijun Duan, Yuncheng Liu et al.
7 citations
Organic Chemistry Frontiers
Cyclopropane Reaction Mechanisms
6.55
article

Catalytic (5 + 1) cycloaddition of diazooxindoles with imidazolidines to access novel piperazine-spirooxindole frameworks

Shiyong Peng, Wendi Xu, Yijun Duan, Yuncheng Liu, Ming Lang, Feng Chen, Xue Zhang
article en
7 citations

Abstract

A rhodium or copper catalyzed (5 + 1) cycloaddition of diazooxindoles with imidazolidines is reported, offering a series of structurally novel piperazine-spirooxindoles. The asymmetric version has also been realized under Cu( ii )/SaBOX system.

Organic Chemistry FrontiersVol. 12(15)
Wuyi University (CN)
Openalex Percentile: Top 3%
Cyclopropane Reaction Mechanisms
6.55
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