Extended Kohler’s scaling and isosbestic point in the charge density wave state of 1T-VSe<sub>2</sub>

1T-VSe<sub>2</sub>is a narrow band transition metal chalcogenide that shows charge density wave (CDW) state below T<sub>CDW</sub>= 110 K. Here, we have explored the relevance of Kohler's rule and the thermal transport properties of VSe<sub>2</sub>across the CDW state in the presence of magnetic field. The magnetoresistance (MR) follows Kohler's rule above T<sub>CDW</sub>, while an extended Kohler's rule is employed below T<sub>CDW</sub>. Interestingly, we observed an anomaly in MR around T ∼ 20 K, below which MR value decreases on lowering temperature. This anomaly is also reflected in the slope (κ) of Kohler's plots and the relative change in the thermal excitation induced carrier density (n<sub>T</sub>). Despite a strong magnetic field of 14 Tesla, the T<sub>CDW</sub>remains largely unaffected in both electrical resistivity (ρ(T)) and Seebeck coefficient (S), although the application of magnetic field does enhance the peak intensity of S around T ∼ 60 K. The crossover of S curves measured at different magnetic fields at T ∼ 20 K suggests the existence of a novel feature within the CDW state of VSe<sub>2</sub>i.e., the presence of a locally exact isosbestic point.

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Journal
Journal of Physics Condensed Matter
Published
2025-03-28
DOI
https://doi.org/10.1088/1361-648x/adc6e4
Primary Topic
Organic and Molecular Conductors Research
Type
article
Field-Weighted Citation Impact
0.00

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article

Extended Kohler’s scaling and isosbestic point in the charge density wave state of 1T-VSe2

C. S. Yadav, A. Taraphder, Sonika Bagga, Pankaj Kumar et al.
Journal of Physics Condensed Matter
Organic and Molecular Conductors Research
article

Extended Kohler’s scaling and isosbestic point in the charge density wave state of 1T-VSe2

C. S. Yadav, A. Taraphder, Sonika Bagga, Pankaj Kumar, Sunil Gangwar
article en

Abstract

1T-VSe<sub>2</sub>is a narrow band transition metal chalcogenide that shows charge density wave (CDW) state below T<sub>CDW</sub>= 110 K. Here, we have explored the relevance of Kohler's rule and the thermal transport properties of VSe<sub>2</sub>across the CDW state in the presence of magnetic field. The magnetoresistance (MR) follows Kohler's rule above T<sub>CDW</sub>, while an extended Kohler's rule is employed below T<sub>CDW</sub>. Interestingly, we observed an anomaly in MR around T ∼ 20 K, below which MR value decreases on lowering temperature. This anomaly is also reflected in the slope (κ) of Kohler's plots and the relative change in the thermal excitation induced carrier density (n<sub>T</sub>). Despite a strong magnetic field of 14 Tesla, the T<sub>CDW</sub>remains largely unaffected in both electrical resistivity (ρ(T)) and Seebeck coefficient (S), although the application of magnetic field does enhance the peak intensity of S around T ∼ 60 K. The crossover of S curves measured at different magnetic fields at T ∼ 20 K suggests the existence of a novel feature within the CDW state of VSe<sub>2</sub>i.e., the presence of a locally exact isosbestic point.

Journal of Physics Condensed MatterVol. 37(19)
Indian Institute of Technology Kharagpur (IN), Indian Institute of Technology Mandi (IN)
Science and Engineering Research Board
Openalex Percentile: Top 97%
Organic and Molecular Conductors Research
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