Advances of Mayer's cluster approach in quantitative theoretical description of phase transitions for various lattice models of matter

Resent achievements in Statistical Theory, namely, a possibility to reproduce almost unlimited Mayer's activity series based on the information about their convergence radius, on the one hand, and generalization of the Lattice Statistics by eliminating the simplification of nearest-neighbor interactions, on the other hand, have allowed accurate quantitative description of the condensation in lattice gases, spontaneous magnetization in ferromagnets, and spinodal decomposition in binary mixtures by evaluating only a several irreducible cluster integrals (virial coefficients). In particular, the results of calculations indicate qualitative and even quantitative universality in the behavior of the mentioned lattice systems of different geometry and dimensionality at the same values of a certain reduced temperature when that behavior is expressed in terms of some dimensionless parameters. An additional possibility to describe the order-disorder phase transitions in some other lattice systems (e.g., antiferromagnets and alloys) is also discussed in the paper.

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Journal
Condensed Matter Physics
Published
2025-03-28
DOI
https://doi.org/10.5488/cmp.28.13501
Primary Topic
Theoretical and Computational Physics
Type
article
Field-Weighted Citation Impact
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article

Advances of Mayer's cluster approach in quantitative theoretical description of phase transitions for various lattice models of matter

M. V. Ushcats, N. Romanchuk, Zhanna Burunina, S. Ushkats et al.
Condensed Matter Physics
Theoretical and Computational Physics
article

Advances of Mayer's cluster approach in quantitative theoretical description of phase transitions for various lattice models of matter

M. V. Ushcats, N. Romanchuk, Zhanna Burunina, S. Ushkats, Л. А. Булавін, O. Maiboroda, N. Shapoval
article en

Abstract

Resent achievements in Statistical Theory, namely, a possibility to reproduce almost unlimited Mayer's activity series based on the information about their convergence radius, on the one hand, and generalization of the Lattice Statistics by eliminating the simplification of nearest-neighbor interactions, on the other hand, have allowed accurate quantitative description of the condensation in lattice gases, spontaneous magnetization in ferromagnets, and spinodal decomposition in binary mixtures by evaluating only a several irreducible cluster integrals (virial coefficients). In particular, the results of calculations indicate qualitative and even quantitative universality in the behavior of the mentioned lattice systems of different geometry and dimensionality at the same values of a certain reduced temperature when that behavior is expressed in terms of some dimensionless parameters. An additional possibility to describe the order-disorder phase transitions in some other lattice systems (e.g., antiferromagnets and alloys) is also discussed in the paper.

Condensed Matter PhysicsVol. 28(1)
Admiral Makarov National University of Shipbuilding (UA), Taras Shevchenko National University of Kyiv (UA)
Openalex Percentile: Top 96%
Theoretical and Computational Physics
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