CH4 conversion to С2-С3 hydrocarbons over Pt/MgAlOх catalysts in a cyclic mode

A dynamics of the reaction of non-oxidative methane coupling at 600 0 C catalyzed by 1%Pt/MgAlOх and 1%Pt/g-Al 2 O 3 with close size of platinum clusters has been studied. In contrast to reference 1%Pt/g-Al 2 O 3 sample, carbonaceous strongly adsorbed compounds accumulated during reaction running can be burnt out completely in 1%Pt/MgAlOх catalysts at the same temperature, which restored their catalytic activity. A possibility to increase the duration of their operation with maximal C2-C3 products yield under cyclic mode and minimal CO and CO 2 formation during regeneration has been shown.

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Publication Details

Journal
Kataliz v promyshlennosti
Published
2025-03-28
DOI
https://doi.org/10.18412/1816-0387-2025-2-68-78
Primary Topic
Catalytic Processes in Materials Science
Type
article
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article

CH4 conversion to С2-С3 hydrocarbons over Pt/MgAlOх catalysts in a cyclic mode

А. С. Носков, O. B. Belskaya, Igor P. Prosvirin, В. А. Лихолобов et al.
Kataliz v promyshlennosti
Catalytic Processes in Materials Science
article

CH4 conversion to С2-С3 hydrocarbons over Pt/MgAlOх catalysts in a cyclic mode

А. С. Носков, O. B. Belskaya, Igor P. Prosvirin, В. А. Лихолобов, L. G. Pinaeva
article en

Abstract

A dynamics of the reaction of non-oxidative methane coupling at 600 0 C catalyzed by 1%Pt/MgAlOх and 1%Pt/g-Al 2 O 3 with close size of platinum clusters has been studied. In contrast to reference 1%Pt/g-Al 2 O 3 sample, carbonaceous strongly adsorbed compounds accumulated during reaction running can be burnt out completely in 1%Pt/MgAlOх catalysts at the same temperature, which restored their catalytic activity. A possibility to increase the duration of their operation with maximal C2-C3 products yield under cyclic mode and minimal CO and CO 2 formation during regeneration has been shown.

Kataliz v promyshlennostiVol. 25(2)
Boreskov Institute of Catalysis (RU)
Openalex Percentile: Top 96%
Catalytic Processes in Materials Science
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