Effect of Working Fluid on Characteristics of Organic Rankine Cycle with Medium Temperature Geothermal Water

The total installed geothermal power plant capacity at year-end 2023 was 16,335 MW, while the forecast for the installed capacity in 2025 is 19,331 MW. In Croatia, several medium-temperature geothermal resources (geothermal water) with temperatures from 90 to 200 °C exist, by means of which it is possible to produce electricity in binary plants, with the Organic Rankine Cycle (ORC) or with the Kalina cycle. In earlier studies, the authors presented the results of an energy-exergy analysis of geothermal sources at Velika Ciglena (170 °C), Lunjkovec-Kutnjak (140 °C), Babina Greda (125 °C), and Rečica (120 °C), aiming to determine which binary plant is more suitable for the environmental conditions in Croatia. The calculations indicate that the plant with ORC is thermodynamically superior to the one with the Kalina cycle for all geothermal sources. Taking into account the typical challenges faced by new technologies during their initial implementation, the authors recommend using the ORC plant for all medium-temperature geothermal sources. Literature on ORC applications mainly addresses working fluid selection, unit and plant optimization, and modifications to enhance thermodynamic efficiency or net power output. While many studies on working fluid selection exist, each geothermal source is unique due to its specific temperature and local cooling fluid (water or air). As a result, this paper presents the findings of an analysis on the influence of working fluids on the thermodynamic performance of an ORC system, focusing on the Lunjkovec-Kutnjak Geothermal Power Plant with a geothermal water temperature of 140 °C. As the working fluid, the next are analyzed: isopentane (C5H12), isobutene (C4H10), isohexane (C6H14), R114 (C2Cl2F4), R141B (C2H3Cl2F), and R142B (C2H3Cl2F2). In respect to cycle efficiency and net power, all working fluids are equally favorable, but R601a (isopentane) with low ALT, ODP, and GWP, favorable upper and lower pressure, is the most suitable fluid for ORC with a medium-temperature geothermal source.