Phase transition temperatures of ternary multiferroics and interatomic bond <i>A</i>–O strains in their perovskite structures

The known multiferroics (MFs)-ternary oxides with perovskite-type structure [Formula: see text] that undergo successive phase transitions (PTs), ferroelectric (FE) or antiferroelectric (AFE) — at the Curie temperature, [Formula: see text], and ferromagnetic (FM), antiferromagnetic (AFM) or ferrimagnetic at the Néel temperature, [Formula: see text] —and classical FEs and AFEs are considered. The dependences of the [Formula: see text], [Formula: see text] on the interatomic bond A–O strains in their perovskite structures have been constructed. On constructed dependencies, some ternary MFs are discovered, which have comparatively high temperatures of first FE or AFE and second magnetic PTs but their difference [Formula: see text]–[Formula: see text] values are high comparatively with the binary MFs.

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Publication Details

Journal
Journal of Advanced Dielectrics
Published
2025-03-27
DOI
https://doi.org/10.1142/s2010135x25400107
Primary Topic
Material Science and Thermodynamics
Type
article
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article

Phase transition temperatures of ternary multiferroics and interatomic bond A–O strains in their perovskite structures

G. A. Geguzina, И. Г. Попова
Journal of Advanced Dielectrics
Material Science and Thermodynamics
article

Phase transition temperatures of ternary multiferroics and interatomic bond A–O strains in their perovskite structures

G. A. Geguzina, И. Г. Попова
article en

Abstract

The known multiferroics (MFs)-ternary oxides with perovskite-type structure [Formula: see text] that undergo successive phase transitions (PTs), ferroelectric (FE) or antiferroelectric (AFE) — at the Curie temperature, [Formula: see text], and ferromagnetic (FM), antiferromagnetic (AFM) or ferrimagnetic at the Néel temperature, [Formula: see text] —and classical FEs and AFEs are considered. The dependences of the [Formula: see text], [Formula: see text] on the interatomic bond A–O strains in their perovskite structures have been constructed. On constructed dependencies, some ternary MFs are discovered, which have comparatively high temperatures of first FE or AFE and second magnetic PTs but their difference [Formula: see text]–[Formula: see text] values are high comparatively with the binary MFs.

Journal of Advanced DielectricsVol. 15(04)
Southern Federal University (RU), Don State Technical University (RU)
Openalex Percentile: Top 94%
Material Science and Thermodynamics
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