A cyclic-triphosphazene based single-ion polymer electrolyte prepared <i>via</i> click reaction for lithium metal batteries
This study presents a rapid preparation method for a self-supporting polymer electrolyte <i>via</i> thiol-ene click reaction. The resulting electrolyte demonstrates a high ionic conductivity of 9.5 × 10<sup>-4</sup> S cm<sup>-1</sup> at 90 °C and a lithium ion transference number of 0.77. The lithium symmetrical battery stably operated for 1200 h at 0.1 mA cm<sup>-2</sup>, significantly suppressing the formation of lithium dendrites.
Authors
- Wei Hu
- Hongbin Li
- Cengliang Shan
- Hui Zhang (ORCID: https://orcid.org/0000-0002-6773-5357)
- Baijun Liu (ORCID: https://orcid.org/0000-0002-9553-0658)
- Xiong Chen (ORCID: https://orcid.org/0000-0003-2878-7522)
- Kuan Lu (ORCID: https://orcid.org/0000-0003-2693-3995)
- Huinan Li (ORCID: https://orcid.org/0009-0001-7024-7645)
Institutions
- Northeast Normal University (CN)
- Jilin University (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc00099h
- Citations
- 3
- Primary Topic
- Advanced Battery Materials and Technologies
- Type
- article
- Field-Weighted Citation Impact
- 2.19