Engineering geometric metamorphosis in {P<sub>6</sub>M<sub>2</sub>Mo<sub>16</sub>O<sub>73</sub>}-based high-nuclearity metal superclusters: from tetrahedral to square assemblies <i>via</i> topological transformations
The precision engineering of the molecular framework has synthesized two superclusters based on the {Sr⊂P 6 M 2 Mo 16 O 73 } motif, which exhibit closely related topological structures: Co12Sr4Mo80P36 and Na4Ni23Sr4Mo88P52.
Authors
- Xiaoyan Zhang (ORCID: https://orcid.org/0000-0002-8336-5579)
- Na Xu (ORCID: https://orcid.org/0000-0001-7447-4581)
- Hongmei Liu (ORCID: https://orcid.org/0000-0003-1064-2448)
- Xiuli Wang (ORCID: https://orcid.org/0000-0002-0308-1403)
- Hui Li (ORCID: https://orcid.org/0000-0002-3339-4216)
Institutions
- Bohai University (CN)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qi00460h
- Citations
- 36
- Primary Topic
- Polyoxometalates: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 18.64
Funders
- National Natural Science Foundation of China