Impact of low NaOH molarities on mechanical and durability properties of ambient and oven-cured fly ash geopolymer concrete

Ambient cured fly ash based geopolymer concrete (GPC) is a promising environmentally friendly alternative to Ordinary Portland Cement Concrete (OPCC). However, adoption of geopolymer concrete has been hampered by the challenges associated with the use of highly concentrated activators and the need for heat curing to achieve sufficient fresh and hardened properties, as well as the limited research on its durability. This paper aims to address these issues by focusing on producing high strength geopolymer concrete using low molarity activators and ambient curing conditions. The effect of curing temperatures and Sodium Hydroxide (NaOH) activator concentrations ranging from 2, 4, 6, and 8 M were evaluated in terms of strength and durability performance. Durability studies examined carbonation, chloride penetration, and abrasion resistance. Porosity and permeability of the concrete mixtures were also investigated through an examination of water absorption and sorptivity performance. Further, SEM analysis clarified the microstructural changes which occurred as a result of differing curing temperatures and NaOH molarities. Lastly, a cost comparison was conducted which compared the costs of all the developed geopolymer mixtures with respect to a reference OPCC mix and significant cost were observed for the GPC mixes compared to OPCC of equivalent strength. • Low NaOH molarities were explored to produce fly ash-based geopolymer concrete cured at ambient temperature. • Durability studies examined carbonation, chloride penetration, and abrasion resistance, water absorption and sorptivity. • SEM analysis revealed microstructural characteristics. • Cost analysis compared geopolymer mixes to Portland cement concrete.

Authors

Publication Details

Journal
Journal of Building Engineering
Published
2025-03-27
DOI
https://doi.org/10.1016/j.jobe.2025.112491
Citations
16
Primary Topic
Concrete and Cement Materials Research
Type
article
Field-Weighted Citation Impact
15.25
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article

Impact of low NaOH molarities on mechanical and durability properties of ambient and oven-cured fly ash geopolymer concrete

Mustafa Shamsah, Kolluru V. L. Subramaniam, Robin Kalfat
16 citations
Journal of Building Engineering
Concrete and Cement Materials Research
15.25
article

Impact of low NaOH molarities on mechanical and durability properties of ambient and oven-cured fly ash geopolymer concrete

Mustafa Shamsah, Kolluru V. L. Subramaniam, Robin Kalfat
article en
16 citations

Abstract

Ambient cured fly ash based geopolymer concrete (GPC) is a promising environmentally friendly alternative to Ordinary Portland Cement Concrete (OPCC). However, adoption of geopolymer concrete has been hampered by the challenges associated with the use of highly concentrated activators and the need for heat curing to achieve sufficient fresh and hardened properties, as well as the limited research on its durability. This paper aims to address these issues by focusing on producing high strength geopolymer concrete using low molarity activators and ambient curing conditions. The effect of curing temperatures and Sodium Hydroxide (NaOH) activator concentrations ranging from 2, 4, 6, and 8 M were evaluated in terms of strength and durability performance. Durability studies examined carbonation, chloride penetration, and abrasion resistance. Porosity and permeability of the concrete mixtures were also investigated through an examination of water absorption and sorptivity performance. Further, SEM analysis clarified the microstructural changes which occurred as a result of differing curing temperatures and NaOH molarities. Lastly, a cost comparison was conducted which compared the costs of all the developed geopolymer mixtures with respect to a reference OPCC mix and significant cost were observed for the GPC mixes compared to OPCC of equivalent strength. • Low NaOH molarities were explored to produce fly ash-based geopolymer concrete cured at ambient temperature. • Durability studies examined carbonation, chloride penetration, and abrasion resistance, water absorption and sorptivity. • SEM analysis revealed microstructural characteristics. • Cost analysis compared geopolymer mixes to Portland cement concrete.

Journal of Building EngineeringVol. 105
Sustainable cities and communities
Openalex Percentile: Top 1%
Concrete and Cement Materials Research
15.25
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Impact of low NaOH molarities on mechanical and durability properties of ambient and oven-cured fly ash geopolymer concrete — Mustafa Shamsah, Kolluru V. L. Subramaniam, et al. · Journal of Building Engineering (2025) | TGRS Research Map | TGRS