Atomic layer deposition of Al <i>x</i> Ti1 <i>−x</i> N via co-evaporation of metal precursors

Different approaches are used in tailoring properties of thin films to meet the requirements of specific applications. This study comprises work done on atomic layer deposition of AlxTi1−xN employing the co-evaporation approach using tris-dimethylamido aluminum [Al(NMe2)3], tetrakis(dimethylamido)titanium (IV) [Ti(NMe2)4], and ammonia (NH3) plasma. High Al-content, low impurity (O and C, both &amp;lt;5 at. %) films with uniform grain size distribution and dense morphology were deposited. The as-deposited films were x-ray amorphous, but mixed crystallographic phases were observed when the films were annealed at 700 °C. The deposited aluminum-rich AlxTi1−xN films show an alternative way for ternary material depositions.

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Publication Details

Journal
Journal of Vacuum Science & Technology A Vacuum Surfaces and Films
Published
2025-03-27
DOI
https://doi.org/10.1116/6.0004420
Citations
1
Primary Topic
Semiconductor materials and devices
Type
article
Field-Weighted Citation Impact
0.73
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article

Atomic layer deposition of Al x Ti1 −x N via co-evaporation of metal precursors

Pamburayi Mpofu, T. Larsson, Pentti Niiranen, Henrik Pedersen et al.
1 citations
Journal of Vacuum Science & Technology A Vacuum Surfaces and Films
Semiconductor materials and devices
0.73
article

Atomic layer deposition of Al x Ti1 −x N via co-evaporation of metal precursors

Pamburayi Mpofu, T. Larsson, Pentti Niiranen, Henrik Pedersen, Oscar Alm, Jonas Lauridsen
article en
1 citations

Abstract

Different approaches are used in tailoring properties of thin films to meet the requirements of specific applications. This study comprises work done on atomic layer deposition of AlxTi1−xN employing the co-evaporation approach using tris-dimethylamido aluminum [Al(NMe2)3], tetrakis(dimethylamido)titanium (IV) [Ti(NMe2)4], and ammonia (NH3) plasma. High Al-content, low impurity (O and C, both &amp;lt;5 at. %) films with uniform grain size distribution and dense morphology were deposited. The as-deposited films were x-ray amorphous, but mixed crystallographic phases were observed when the films were annealed at 700 °C. The deposited aluminum-rich AlxTi1−xN films show an alternative way for ternary material depositions.

Journal of Vacuum Science & Technology A Vacuum Surfaces and FilmsVol. 43(3)
Linköping University (SE)
Openalex Percentile: Top 30%
Semiconductor materials and devices
0.73
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Atomic layer deposition of Al <i>x</i> Ti1 <i>−x</i> N via co-evaporation of metal precursors — Pamburayi Mpofu, T. Larsson, et al. · Journal of Vacuum Science & Technology A Vacuum Surfaces and Films (2025) | TGRS Research Map | TGRS