Visible-Light-Induced Radical Hydroaroylation of Vinyl Boronic Ester with Aroyl Chlorides to Access β-Boryl Ketones
A visible-light-induced radical hydroaroylation of vinyl boronic ester with aroyl chlorides has been developed, yielding a variety of β-boryl ketones in moderate to good yields with broad functional group tolerance. This metal-free transformation offers a convenient and practical route to access valuable β-boryl ketones from readily available aroyl chlorides and vinyl boronic ester.
Authors
- Shuai Tang (ORCID: https://orcid.org/0000-0003-0086-9104)
- Hua Zhang (ORCID: https://orcid.org/0000-0002-4960-0838)
- Shuting Wang (ORCID: https://orcid.org/0000-0003-4137-5821)
Institutions
- Minzu University of China (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2025-03-26
- DOI
- https://doi.org/10.1021/acs.orglett.5c00996
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00