Heterojunction constructed from ZIF-8-on-MIL-68(Ga) precursor for photocatalytic CO<sub>2</sub> reduction

Herein, a ZIF-8-on-MIL-68(Ga) precursor derived ZnGa<sub>2</sub>O<sub>4</sub>/ZnO heterojunction can promote charge separation and has a strong photoredox ability, while decoration with a Au cocatalyst can lower the Gibbs free energy barrier of the rate-determining step in the photocatalytic CO<sub>2</sub> reduction reaction, leading to a high CH<sub>4</sub> yield of 21.1 μmol g<sup>-1</sup> h<sup>-1</sup> in pure water without any sacrificial reagent.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc00705d
Citations
1
Primary Topic
Advanced Photocatalysis Techniques
Type
article
Field-Weighted Citation Impact
0.36
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article

Heterojunction constructed from ZIF-8-on-MIL-68(Ga) precursor for photocatalytic CO2 reduction

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1 citations
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Advanced Photocatalysis Techniques
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article

Heterojunction constructed from ZIF-8-on-MIL-68(Ga) precursor for photocatalytic CO2 reduction

Juncheng Hu, Kangle Lv, Yi Liu, Qin Li, Yu Ma, Hao Yu, Xiaole Han, Qingqing Jiang, Xingyu Li
article en
1 citations

Abstract

Herein, a ZIF-8-on-MIL-68(Ga) precursor derived ZnGa<sub>2</sub>O<sub>4</sub>/ZnO heterojunction can promote charge separation and has a strong photoredox ability, while decoration with a Au cocatalyst can lower the Gibbs free energy barrier of the rate-determining step in the photocatalytic CO<sub>2</sub> reduction reaction, leading to a high CH<sub>4</sub> yield of 21.1 μmol g<sup>-1</sup> h<sup>-1</sup> in pure water without any sacrificial reagent.

Chemical CommunicationsVol. 61(37)
Minzu University of China (CN)
Affordable and clean energy
Openalex Percentile: Top 45%
Advanced Photocatalysis Techniques
0.36
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