Ni-catalyzed reductive carbonylation of ethylene with CO <sub>2</sub> and methanol: potential for <i>in situ</i> CO <sub>2</sub> capture and conversion
Ni catalysis outperforms noble metals through combining CO 2 /ethylene coupling to nickelalactone and alcoholytic ring-opening, enabling noble metal-, halide-, and strong reductant-free CO 2 -based carbonylation for sustainable production of polymers.
Authors
- Y. Lai (ORCID: https://orcid.org/0000-0002-7795-8693)
- Haozhi Zhou
- Shunan Zhang (ORCID: https://orcid.org/0000-0002-2385-0767)
- Yuhan Sun (ORCID: https://orcid.org/0000-0002-2940-213X)
- Hui Wang (ORCID: https://orcid.org/0000-0002-5208-8329)
- Xiaofang Liu (ORCID: https://orcid.org/0000-0002-5923-6865)
- Junjun Chen
- Hu Luo (ORCID: https://orcid.org/0000-0002-6504-5061)
- Yuqi Yang (ORCID: https://orcid.org/0009-0009-6902-5533)
Institutions
- Chinese Academy of Sciences (CN)
- ShanghaiTech University (CN)
- Shanghai Advanced Research Institute (CN)
Publication Details
- Journal
- Green Chemistry
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d4gc06460g
- Citations
- 1
- Primary Topic
- Carbon dioxide utilization in catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.70