On the high-momentum oscillatory distribution and related quantum information theoretical measures of confined alkali systems (H, Li)

Abstract The effect of impenetrable spherical confinement on alkali systems (H, Li) has been thoroughly examined, emphasizing the distinctive high-momentum oscillatory behavior of the momentum space radial density. We have utilized the Ritz variational framework with a Slater-type basis set to derive the position-space wavefunction and Fourier–Dirac transformation of the former to find the momentum-space wavefunction, analytically. The derived momentum-space density has been analyzed in four asymptotic limits ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>R</mml:mi> <mml:mo stretchy="false">→</mml:mo> <mml:mi mathvariant="normal">∞</mml:mi> </mml:mrow> </mml:math> , <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>R</mml:mi> <mml:mo stretchy="false">→</mml:mo> <mml:mn>0</mml:mn> </mml:mrow> </mml:math> , <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>p</mml:mi> <mml:mo stretchy="false">→</mml:mo> <mml:mi mathvariant="normal">∞</mml:mi> </mml:mrow> </mml:math> , and <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>p</mml:mi> <mml:mo stretchy="false">→</mml:mo> <mml:mn>0</mml:mn> </mml:mrow> </mml:math> ; R being the confinement radius and p being the radial component of linear momentum) and its oscillatory behavior in strong spatial confinement region is critically investigated. Oscillatory behavior is also noticed in the Compton profile of the compressed atomic system. Furthermore, the effects of confinement on Shannon information entropy in both position and momentum spaces are investigated, offering insights into the Bialynicki–Birula–Mycielski inequality and the local variations of information measures in terms of Shannon entropy density.