Rh(<scp>iii</scp>)-catalyzed C–H alkenylation of NH-sulfoximine with vinylsilanes

The rhodium(III)-catalysed <i>ortho</i>-C-H alkenylation of NH-sulfoximine using readily available vinylsilanes as an olefinating reagent to introduce vinylsilane groups has been achieved. These groups are adaptable synthetic intermediates, and can be selectively changed into a variety of substituents.

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Publication Details

Journal
Organic & Biomolecular Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5ob00213c
Citations
1
Primary Topic
Synthesis and Catalytic Reactions
Type
article
Field-Weighted Citation Impact
0.94
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article

Rh(iii)-catalyzed C–H alkenylation of NH-sulfoximine with vinylsilanes

Lin Dong, Yu Gao, Yali Xu
1 citations
Organic & Biomolecular Chemistry
Synthesis and Catalytic Reactions
0.94
article

Rh(iii)-catalyzed C–H alkenylation of NH-sulfoximine with vinylsilanes

Lin Dong, Yu Gao, Yali Xu
article en
1 citations

Abstract

The rhodium(III)-catalysed <i>ortho</i>-C-H alkenylation of NH-sulfoximine using readily available vinylsilanes as an olefinating reagent to introduce vinylsilane groups has been achieved. These groups are adaptable synthetic intermediates, and can be selectively changed into a variety of substituents.

Organic & Biomolecular ChemistryVol. 23(16)
Sichuan University (CN)
Openalex Percentile: Top 28%
Synthesis and Catalytic Reactions
0.94
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