Intramolecular and intermolecular benzannulation of arylethanone derivatives enabled by visible light-induced catalytic generation of tether-tunable distonic radical anions
A novel method enables inter-/intramolecular benzannulation to synthesize PAHs have been disclosed. Experimental and DFT data confirm the TDRA's role in the HAA step of enolized 1,3-dicarbonyls via asynchronous PCET.
Authors
- Ziye Zhan
- Lei Shi (ORCID: https://orcid.org/0000-0002-6865-1104)
- Kang Fu (ORCID: https://orcid.org/0000-0003-4425-8110)
- Zhiyou Yu
Institutions
- Harbin Institute of Technology (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5qo00271k
- Citations
- 1
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.94
Funders
- National Natural Science Foundation of China